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I've been listening to these for about a year now and they are mostly all good. A few of the more epic ones I can remember:

Chael sonnen - lots of interesting stories, very intelligent and entertaining.
Any episode with Joey Diaz - Most hilarious member of the deathsquad crew
Bas rutton - MMA legend, hilarious commentator
Ronda Roussey - recorded right before she won her title. Bad ass chick - olympic medalist in Judo and MMA champion
Everlast - Awesome acoustic performances of his songs
Honey honey - another awesome musical performance guest
Jim Jefferies - hilarious australian comedian. Very redpill in his views.